Nonadiabatic transition probabilities in the presence of strong dissipation at an avoided-level crossing point
نویسندگان
چکیده
منابع مشابه
Investigation of Temperature Effect in Landau-Zener Avoided Crossing
Considering a temperature dependent two-level quantum system, we have numerically solved the Landau-Zener transition problem. The method includes the incorporation of temperature effect as a thermal noise added Schrödinger equation for the construction of the Hamiltonian. Here, the obtained results which describe the changes in the system including the quantum states and the transition pro...
متن کاملTrajectory-based nonadiabatic molecular dynamics without calculating nonadiabatic coupling in the avoided crossing case: trans↔cis photoisomerization in azobenzene.
We develop a novel method to simulate analytical nonadiabatic switching probability based on effective coupling and effective collision energy by using only electronic adiabatic potential energy surfaces and its gradients in the case of avoided crossing types of nonadiabatic transitions. In addition, the present method can keep the same time step for computing both on-the-fly trajectory and non...
متن کاملAvoided-level-crossing statistics in open chaotic billiards.
We investigate a two-level model with a large number of open decay channels in order to describe avoided level crossing statistics in open chaotic billiards. This model allows us to describe the fundamental changes in the probability distribution of the avoided level crossings compared with the closed case. Explicit expressions are derived for systems with preserved and broken time-reversal sym...
متن کاملCavity Femtochemistry: Manipulating Nonadiabatic Dynamics at Avoided Crossings.
Molecular potential energy surfaces can be actively manipulated by light. This is usually done by strong classical laser light but was recently demonstrated for the quantum field in an optical cavity. The photonic vacuum state of a localized cavity mode can be strongly mixed with the molecular degrees of freedom to create hybrid field-matter states known as polaritons. We simulate the avoided c...
متن کاملMonitoring nonadiabatic avoided crossing dynamics in molecules by ultrafast X-ray diffraction
We examine time-resolved X-ray diffraction from molecules in the gas phase which undergo nonadiabatic avoided-crossing dynamics involving strongly coupled electrons and nuclei. Several contributions to the signal are identified, representing (in decreasing strength) elastic scattering, contributions of the electronic coherences created by nonadiabatic couplings in the avoided crossing regime, a...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical Review A
سال: 2002
ISSN: 1050-2947,1094-1622
DOI: 10.1103/physreva.65.033407